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 ohnap portal|Login The principal quantum shells increase in energy with increasing principal quantum number. E.g. n = 4 is higher in energy than n = 2 The subshells increase in energy as follows: s ＜ p ＜ d ＜ f. The only exception to these rules is the 3d orbital which has slightly higher energy than the 4s orbital; Because of this, the 4s orbital is filled before the 3d orbital

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